Modular synthesis of thiazoline and thiazole derivatives by using a cascade protocol† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c7ra05993k

Organocatalytic, enantioselective synthesis of benzoxaboroles via Wittig/oxa-Michael reaction Cascade of α-formyl boronic acids† †Electronic supplementary information (ESI) available. CCDC 1487136. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c6sc04522g Click here for additional data file. Click here for additional data file.

Hyperpolarization of amino acid derivatives in water for biological applications† †Electronic supplementary information (ESI) available: Synthesis, para-hydrogen experiments, relaxation times of amino acid derivatives, catalyst decomposition and remarks on amino acid PHIP. See DOI: 10.1039/c5sc00503e

A practical and scalable system for heteroaryl amino acid synthesis† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c7sc03612d

A robust system for the preparation of β-heteroaryl α-amino acid derivatives has been developed using photoredox catalysis. This system operates via regiospecific activation of halogenated pyridines (or other heterocycles) and conjugate addition to dehydroalanine derivatives to deliver a wide range of unnatural amino acids. This process was conducted with good efficiency on large scale, the app...

Catalytic asymmetric hydroxylative dearomatization of 2-naphthols: synthesis of lacinilene derivatives† †Electronic supplementary information (ESI) available. CCDC 1536822. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7sc02809a Click here for additional data file. Click here for additional data file.

Watasemycin biosynthesis in Streptomyces venezuelae: thiazoline C-methylation by a type B radical-SAM methylase homologue† †Electronic supplementary information (ESI) available: Experimental procedures and additional tables, figures, chromatograms and results from biological assays. See DOI: 10.1039/c6sc03533g Click here for additional data file.

Department of Chemistry, University of War [email protected] Kitasato Institute for Life Sciences, Kitasato Tokyo, Japan Department of Molecular Microbiology, Joh E-mail: [email protected] † Electronic supplementary information ( and additional tables, gures, chromatogr See DOI: 10.1039/c6sc03533g ‡ These authors contributed equally. § Current address: Department of Bioeng Diego, USA. ...